SAFETY DATA SHEET
**** SECTION 1 - IDENTIFICATION
****
Material
Name: Cobalt
Company
Identification: ACI ALLOYS INC
1458 Seareel Place
San Jose, CA 95131
For information, call:
408-259-7337
Emergency
Number
For
CHEMTREC assistance, call: 800-424-9300
For
International CHEMTREC assistance, call: 703-527-3887
**** SECTION 2 -
HAZARDS IDENTIFICATION ****
EMERGENCY
OVERVIEW
May
cause sensitization by inhalation and skin contact.
Potential
Health Effects
Eye:
Causes eye irritation. May
cause conjunctivitis.
Skin:
Prolonged and/or repeated contact may cause
irritation and/or dermatitis. May cause skin sensitization, an allergic reaction,which becomes evident
upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause allergic reaction.
Inhalation:
Causes respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the
respiratory tract. May cause asthma and shortness of
breath.
Chronic:
Repeated exposure may cause sensitization
dermatitis. Repeated exposure may cause allergic respiratory reaction (asthma).
Chronic inhalation of dust may lead to restricted pulmonary function and
interstitial fibrosis.
****
SECTION 3 - COMPOSITION, INFORMATION ON INGREDIENTS ****
CAS# |
Chemical
Name |
% |
EINECS# |
7440-48-4 |
COBALT |
100 |
231-158-0 |
Hazard Symbols: XN
Risk Phrases: 42/43
****
SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
aid.
Skin:
Get medical aid. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to
an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. Get
medical aid if cough or other symptoms appear.
Notes to Physician: NA
**** SECTION 5 -
FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing
apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form explosive mixtures
with air. Material can spontaneously ignite (pyrophoric) when exposed to air at
normal or slightly elevated temperatures. Flammable solid.
Extinguishing Media:
Use dry sand or earth to smother fire.
DO NOT USE WATER!
**** SECTION 6 -
ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as
indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable
disposal container. Avoid generating dusty conditions.
**** SECTION 7 -
HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with skin and eyes. Keep container
tightly closed. Avoid ingestion and inhalation.
Storage:
Keep away from sources of ignition. Keep from
contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION
8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to
keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described
by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European
Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL
PROPERTIES ****
Physical
State: Solid
Appearance:
silver gray or bluish white or black
Odor:
none reported
pH:
Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: Not applicable.
Evaporation
Rate: Not available.
Viscosity:
Not applicable.
Boiling
Point: 5198 deg F
Freezing/Melting
Point: 2723 deg F
Autoignition Temperature:
Not applicable.
Flash
Point: Not applicable.
Explosion
Limits, lower: Not available.
Explosion
Limits, upper: Not available.
Decomposition
Temperature: Not available.
Solubility:
Insoluble in water.
Specific
Gravity/Density: 8.92
Molecular
Formula:Co
Molecular
Weight: 58.9332
**** SECTION 10 - STABILITY
AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust
generation, strong acids, oxidizers.
Incompatibilities with Other Materials:
Pyrophoric cobalt decomposes acetylene
in the cold and the metal becomes incandescent. Fused ammonium nitrate can
react explosively with powdered cobalt.
Hazardous Decomposition Products:
Oxides of cobalt.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 -
TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-48-4: GF8750000
LD50/LC50:
CAS# 7440-48-4: Oral, rat: LD50 = 6171 mg/kg.
Carcinogenicity:
COBALT -
ACGIH: A3 - animal carcinogen
California: carcinogen; initial date 7/1/92
OSHA: Possible Select carcinogen
IARC: Group 2B carcinogen
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Neurotoxicity:
No data available.
Mutagenicity:
No data available.
Other Studies:
No data available.
**** SECTION 12 -
ECOLOGICAL INFORMATION ****
No data available.
**** SECTION 13 -
DISPOSAL CONSIDERATIONS ****
Dispose
of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 -
TRANSPORT INFORMATION ****
US DOT
Shipping Name: OS
Canadian TDG
No information available.
**** SECTION 15 -
REGULATORY INFORMATION ****
US
FEDERAL
TSCA
CAS# 7440-48-4 is listed on the TSCA inventory.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as
Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as
Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as
Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered
highly hazardous
by OSHA.
STATE
COBALT can be found on the following state right to
know lists:
California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
The following statement(s) is(are) made in
order to comply with the California Safe Drinking Water Act:
WARNING: This product contains COBALT, a chemical known to
the state of California to cause cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International
Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 42/43 May cause sensitization by inhalation
and
skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 7440-48-4: 1
United Kingdom Occupational Exposure Limits
Canada
Revised 12/12/15 CJA.
CAS# 7440-48-4 is listed on Canada's DSL List.
CAS# 7440-48-4 is listed on Canada's Ingredient
Disclosure List.
Exposure Limits
CAS# 7440-48-4: OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3
OEL-AUSTRALIA:TWA 0.05 mg/m3
OEL-BELGIUM:TWA 0.05 mg/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg/m3;STEL 0.1 mg/m3
OEL-DENMARK:TWA 0.05 mg/m3
OEL-FINLAND:TWA 0.05 mg/m3;Skin
OEL-GERMANY;Carcinogen
OEL-HUNGARY:TWA 0.1 mg/m3;STEL 0.2 mg/m3
OEL-THE NETHERLANDS:TWA 0.1 mg/m3
OEL-THE PHILIPPINES:TWA 0.1 mg/m3
OEL-POLAND:TWA 0.05 mg/m3
OEL-RUSSIA:STEL 0.5 mg/m3
OEL-SWEDEN:TWA 0.05 mg/m3
OEL-SWITZERLAND:TWA 0.1 mg/m3;Carcinogen
OEL-UNITED KINGDOM:TWA 0.1 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH
TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI
TLV
**** SECTION 16 -
OTHER INFORMATION ****
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In
no way shall the company be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if the company has
been advised of the possibility of such damages.
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